Nicolaou, K. C. ; Li, Yiwei ; Uesaka, Noriaki ; Koftis, Theocharis V. ; Vyskocil, Stepan ; Ling, Taotao ; Govindasamy, Mugesh ; Qian, Wenyuan ; Bernal, Federico ; Chen, David Y. -K. (2003) Total synthesis of the proposed azaspiracid-1 structure. Part 1. Construction of the enantiomerically pure C1-C20, C21-C27, and C28-C40 fragments Angewandte Chemie International Edition, 42 (31). pp. 3643-3648. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...
Related URL: http://dx.doi.org/10.1002/anie.200351825
Abstract
As a build-up to the synthesis of the proposed structure of azaspiracid, both enantiomers of fragments 2, 3, and 4 were synthesized stereoselectively. Piv=pivaloyl, PFP=pentafluorophenyl, Teoc=2-(trimethylsilyl)ethoxycarbonyl, TES=triethylsilyl.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Asymmetric Synthesis; Azaspiracid-1; Natural Products; Neurotoxins; Structural Revision; Total Synthesis |
| ID Code: | 79337 |
| Deposited On: | 25 Jan 2012 06:04 |
| Last Modified: | 25 Jan 2012 06:04 |
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