Mukhopadhyay, Anindita ; Karkamkar, Abhijeet ; Kolehmainen, Erkki ; Rao, Chebrolu P. (1998) Transition metal-saccharide chemistry: synthesis, characterization and solution stability studies of cis-dioxomolybdenum saccharide complexes Carbohydrate Research, 311 (3). pp. 147-154. ISSN 0008-6215
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0008-6215(98)00186-4
Abstract
Six cis-dioxomolybdenum(VI) complexes of simple monosaccharides (D-glucose, D-fructose, D-galactose, D-mannose, D-ribose and D-xylose) have been synthesized and characterized by a variety of analytical and spectral methods. Both the solution and solid-state studies have supported the presence of dimeric structures, formed through the cis-MoO2 moieties and the bridging saccharide units. Solution stability of these complexes as a function of time has also been addressed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Transition Metal-saccharide Chemistry; cis-Dioxomolybdenum Saccharides; Solution Stability; Dimeric Structure; Bridging Saccharide Units |
| ID Code: | 79208 |
| Deposited On: | 24 Jan 2012 15:21 |
| Last Modified: | 19 Apr 2012 05:44 |
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