Gopinath, Purushothaman ; Debasree, Chanda ; Vidyarini, Ravindran Sasitha ; Chandrasekaran, Srinivasan (2010) Synthesis of S-functionalized thioesters using thioaroylate ions derived from carboxylic acids and tetrathiomolybdate via acyloxyphosphonium intermediates Tetrahedron, 66 (34). pp. 7001-7011. ISSN 0040-4020
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/j.tet.2010.06.028
Abstract
Thioaroylate ions generated in situ from acyloxyphosphonium salts and tetrathiomolybdate upon Michael addition or ring opening of three membered systems led to a facile synthesis of S-functionalized thioesters. While the ring opening of aziridines gave very good yield of the products, Michael addition and epoxide ring opening gave moderate yields.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Carboxylic Acids; Michael Addition; Ring Opening; Sulfur; Molybdenum |
| ID Code: | 7331 |
| Deposited On: | 25 Oct 2010 11:47 |
| Last Modified: | 01 Feb 2011 08:19 |
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