Chakraborty, Tushar Kanti ; Sreekanth, Midde ; Pulukuri, Kiran Kumar (2011) Synthetic studies toward potent cytostatic macrolide rhizopodin: Stereoselective synthesis of the C16-C28 fragment Tetrahedron Letters, 52 (1). pp. 59-61. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2010.10.142
Abstract
A stereoselective synthesis of the C16–C28 fragment of cytostatic C2-symmetric macrolide rhizopodin is described. Enantioselective addition of a chiral thiazolidinethione derived titanium enolate to acetal, Evans’ aldol reaction, Horner–Wadsworth–Emmons reaction, and Mukaiyama aldol reaction were applied as key steps.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Rhizopodin; Cytostatic; Actin Polymerization; Inhibitor; Diolides; Aldol Reaction |
| ID Code: | 69574 |
| Deposited On: | 18 Jan 2012 12:17 |
| Last Modified: | 18 Jan 2012 12:17 |
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