Sabitha, Gowravaram ; Gopal, Peddabuddi ; Yadav, Jhillu S. (2009) Total synthesis of the marine polypropionaes, siphonarienal, siphonarienone and pectinatone Tetrahedron: Asymmetry, 20 (19). pp. 2205-2210. ISSN 0957-4166
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetasy.2009.08.021
Abstract
The synthesis of the marine natural products, siphonarienal, siphonarienone, and pectinatone is described employing desymmetrization strategy to create three consecutive stereogenic centers. The key intermediate 7 was made by asymmetric hydroboration of the known meso-olefin using (-)-IPC2BH followed by PCC and Baeyer-Villiger oxidation reactions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 63172 |
| Deposited On: | 28 Sep 2011 03:42 |
| Last Modified: | 28 Sep 2011 03:42 |
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