Sabitha, Gowravaram ; Yadagiri, K. ; Chandrashekhar, G. ; Yadav, J. S. (2010) Synthetic studies on callipeltin A: stereoselective synthesis of (2R,3R,4S)-3-hydroxy-2, 4, 6-trimethylheptanoic acid Synthesis, 2010 (24). pp. 4307-4311. ISSN 0039-7881
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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-0030-1258315
Abstract
Asymmetric synthesis of (2R,3R,4S)-3-hydroxy-2,4,6-trimethylheptanoic acid, the β-hydroxy acid unit that acylates the N-terminus of cyclic depsipeptide callipeltin A, has been devised. The approach involves the desymmetrization of a bicyclic precursor, which generates the three chiral centers.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Asymmetric Synthesis; Callipeltin A; Desymmetrization; Natural Products |
| ID Code: | 63114 |
| Deposited On: | 28 Sep 2011 03:43 |
| Last Modified: | 28 Sep 2011 03:43 |
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