Yadav, Jhillu S. ; Rao, Ragam Nageshwar ; Somaiah, Ragam ; Harikrishna, Valaboju ; Subba Reddy, Basi V. (2010) Stereoselective total synthesis of goniothalesdiol A via chiron approach Helvetica Chimica Acta, 93 (7). pp. 1362-1368. ISSN 0018-019X
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/hlca.20...
Related URL: http://dx.doi.org/10.1002/hlca.200900342
Abstract
The stereocontrolled synthesis of goniothalesdiol A, a dihydroxylated tetrahydropyran compound, has been accomplished using D-ribose as chiral precursor. The key steps involved are aryl Grignard reaction, stereoselective alkoxy-directed keto reduction, and intramolecular oxy-Michael addition.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | D-Ribose; Horner-Wadsworth-Emmons Olefination; Hydroboration; Oxy-Michael Addition; Goniothalesdiol A; Stereoselective Total Synthesis |
| ID Code: | 63091 |
| Deposited On: | 28 Sep 2011 03:49 |
| Last Modified: | 28 Sep 2011 03:49 |
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