Sabitha, Gowravaram ; Syamala, Mandali ; Yadav, J. S. (1999) A mild, efficient, inexpensive, and selective cleavage of primary tert-butyldimethylsilyl ethers by oxone in aqueous methanol Organic Letters, 1 (11). pp. 1701-1703. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol990140h
Related URL: http://dx.doi.org/10.1021/ol990140h
Abstract
The use of a 50% aqueous methonolic solution of Oxone is described for the selective cleavage of primary tert-butyldimethylsilyl and aryl ethers at room temperature. This method enables one to deprotect tert-butyldimethylsilyl ethers of primary alcohols in the presence of tert-butyldimethylsilyl ethers of secondary and tertiary alcohols and phenols. The silyl ethers of phenols were deprotected at longer reaction times.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 60447 |
| Deposited On: | 09 Sep 2011 03:48 |
| Last Modified: | 09 Sep 2011 03:48 |
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