Srikrishna, A. ; Anebouselvy, K. (2002) An enantiospecific approach to (+)-thaps-8(11)-en-3-ol Tetrahedron Letters, 43 (15). pp. 2769-2771. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4039(02)00382-9
Abstract
An enantiospecific synthesis of a thapsane containing an oxygen substituent at the C-3 position is accomplished starting from (R)-carvone. A Claisen rearrangement and an intramolecular diazoketone cyclopropanation reaction were employed for the stereo- and regiospecific generation of the three contiguous quaternary carbon atoms present in the thapsanes.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 48761 |
| Deposited On: | 15 Jul 2011 11:41 |
| Last Modified: | 15 Jul 2011 11:41 |
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