Geochemistry of sericite deposits at the base of the Paleoproterozoic Aravalli Supergroup, Rajasthan, India: evidence for metamorphosed and metasomatised Precambrian Paleosol

Abstract

Fine grained sericite deposits occur at the interface between Archean Mewar Gneiss Complex and the Proterozoic Aravalli Supergroup independent of shearing. They show a gradational contact with the basement granites and gneisses and a sharp contact with the overlying quartz pebble conglomeratic quartzites. Rip-up clasts of these sericite schists are found in the overlying conglomerates. The sericite schists are rich in sericite towards the top and contain chlorite towards the base. The sericite in these schists was formed by metasomatic alteration of kyanite and not from the feldspars of the basement granitoids and gneisses. Uni-directional variations of SiO₂ and Al₂O₃, high Al₂O₃ content (>30%), positive correlation between Al₂O₃ and TiO₂, Ti/Al and Ti/Zr ratios, high pre-metasomatic chemical indices of alteration (>90), and enrichment of heavy rare earth elements relative to the parent granites and gneisses-all these chemical characteristics combined with field evidence suggest that the sericite schists are formed from a paleosol protolith, which developed on Archean basement between 2.5 and ~2.1 Ga in the Precambrian of Rajasthan. The superimposed metasomatic alteration restricts the use of Fe²⁺/Ti and Fe³⁺/Ti ratios of these paleosols for interpretation of PO₂ conditions in the atmosphere.