Narayanan, V. ; Natarajan, P. (1992) Photochemistry of macromolecular metal complexes. III. Synthesis, spectral and electrochemical properties of macromolecular bound protoporphyrin in aqueous solution Journal of Polymer Science Part A: Polymer Chemistry, 30 (12). pp. 2475-2488. ISSN 0887-624X
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/pola.19...
Related URL: http://dx.doi.org/10.1002/pola.1992.080301201
Abstract
The macromolecular bound protoporphyrin IX and its metal complexes, poly-(protoporphyrin-co-acrylamide), cobalt(II) [poly(protoporphyrin-co-acrylamide)], zinc-(II)[poly(protoporphyrin-co-acrylamide)], and manganese(III) [poly(protoporphyrin-co-acrylamide)] chloride were synthesized. The absorption and emission spectra have been obtained for the macromolecular porphyrins. The lifetime of the excited singlet state of the protoporphyrin IX was found to decrease from 13.7 to 6.2 ns after polymerization. The cyclic voltammograms of polymeric protoporphyrin coated electrodes have been obtained.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| Keywords: | Photochemistry; Porphyrin; Macromolecules; Metal Complexes |
| ID Code: | 24406 |
| Deposited On: | 29 Nov 2010 08:59 |
| Last Modified: | 10 Jun 2011 05:54 |
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