Stable and Reusable Palladium Nanoparticles-Catalyzed Conjugate Addition of Aryl Iodides to Enones: Route to Reductive Heck Products

Parveen, Naziya ; Saha, Rajib ; Sekar, Govindasamy (2017) Stable and Reusable Palladium Nanoparticles-Catalyzed Conjugate Addition of Aryl Iodides to Enones: Route to Reductive Heck Products Advanced Synthesis & Catalysis, 359 (21). pp. 3741-3751. ISSN 1615-4150

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Official URL: http://doi.org/10.1002/adsc.201700823

Related URL: http://dx.doi.org/10.1002/adsc.201700823

Abstract

An efficient, binaphthyl-backbone-stabilized palladium nanoparticles (Pd-BNP) catalyst for the 1,4-addition of aryl halides to enones has been developed. The scope of the reaction has been studied with various substituted and sterically hindered aryl halides and enones to afford the conjugate addition products in good to excellent yields. The catalyst has been recovered and reused up to five times without any appreciable change in particle size or reactivity.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons, Inc.
ID Code:132708
Deposited On:21 Dec 2022 06:48
Last Modified:21 Dec 2022 06:48

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