ChemInform Abstract: Radical Cyclization in Stereospecific Introduction of Chirality at “Off Template Site” of 1,2-O-Isopropylidene-α-D-xylo-hexofuranose.

RAO, A. V. R. ; YADAV, J. S. ; RAO, C. S. ; CHANDRASEKHAR, S. (2016) ChemInform Abstract: Radical Cyclization in Stereospecific Introduction of Chirality at “Off Template Site” of 1,2-O-Isopropylidene-α-D-xylo-hexofuranose. ChemInform, 21 (31). ISSN 09317597

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Official URL: http://doi.org/10.1002/chin.199031288

Related URL: http://dx.doi.org/10.1002/chin.199031288

Abstract

The bromoacetal (IV) undergoes facile free radical cyclization to give the cyclic olefinic acetal (V), which is chemically manipulated to introduce either of the chiralities at C-5 of the α-D-hexofuranoses (VI) and (VII).

Item Type:Article
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Deposited On:07 Dec 2022 03:04
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