Yadagiri, Dongari ; Anbarasan, Pazhamalai (2013) Rhodium-Catalyzed Denitrogenative [2,3] Sigmatropic Rearrangement: An Efficient Entry to Sulfur-Containing Quaternary Centers Chemistry - A European Journal, 19 (45). pp. 15115-15119. ISSN 0947-6539
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Official URL: http://doi.org/10.1002/chem.201302653
Related URL: http://dx.doi.org/10.1002/chem.201302653
Abstract
Chemical building blocks: α-Sulfenylated imines containing a quaternary center, an ubiquitous subunit and excellent building block, were achieved by rhodium-catalyzed denitrogenative [2,3] sigmatropic rearrangements of N-sulfonyl-1,2,3-triazoles with allylaryl(alkyl) sulfides. Coupling of this methodology with a copper-catalyzed cycloaddition reaction provides a platform for the direct regioselective functionalization of alkynes (see scheme; TC=thiophenecarboxylate; Ts=p-toluenesulfonyl).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| ID Code: | 130278 |
| Deposited On: | 05 Dec 2022 06:10 |
| Last Modified: | 05 Dec 2022 06:10 |
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