Basavaiah, Deevi ; Reddy, Guddeti Chandrashekar ; Lingaiah, Balthu ; Naganaboina, Ram Tilak (2017) Highly diastereoselective synthesis of tertiary alcohols via intramolecular Baylis-Hillman reaction using less reactive acrylamides as activated alkenes and ketones as electrophiles Tetrahedron, 73 (7). pp. 859-867. ISSN 0040-4020
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Official URL: http://doi.org/10.1016/j.tet.2016.12.069
Related URL: http://dx.doi.org/10.1016/j.tet.2016.12.069
Abstract
A simple and convenient protocol for highly diastereoselective intramolecular Baylis-Hillman (IBH) reaction of substrates containing less reactive acrylamides as activated alkene and ketones with α-chiral center (racemic) as electrophile components, thus producing α-methylene-γ-lactam frameworks having β-tertiary alcoholic functional group, has been developed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 130140 |
| Deposited On: | 02 Dec 2022 05:57 |
| Last Modified: | 05 Dec 2022 05:56 |
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