Roy, Tony ; Gaykar, Rahul N. ; Bhattacharjee, Subrata ; Biju, Akkattu T. (2019) The aryne Sommelet–Hauser rearrangement Chemical Communications, 55 (20). pp. 3004-3007. ISSN 1359-7345
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Official URL: http://doi.org/10.1039/C9CC00629J
Related URL: http://dx.doi.org/10.1039/C9CC00629J
Abstract
An aryne induced transition-metal-free and mild Sommelet–Hauser rearrangement of tertiary benzylamines for the synthesis of α-aryl amino acid derivatives in moderate to good yields is presented. Unlike the conventional Sommelet–Hauser rearrangement of ammonium salts, the methodology developed herein requires neither harsh conditions nor strong bases. Moreover, a temperature dependent switchable selectivity for the Sommelet–Hauser and Stevens [1,2] rearrangements has been observed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry |
| ID Code: | 128608 |
| Deposited On: | 03 Nov 2022 06:44 |
| Last Modified: | 03 Nov 2022 06:44 |
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