Nakao, Yoshiaki ; Oda, Takuro ; K. Sahoo, Akhila ; Hiyama, Tamejiro (2003) Triallyl(aryl)silanes serve as a convenient agent for silicon-based cross-coupling reaction of aryl halides Journal of Organometallic Chemistry, 687 (2). pp. 570-573. ISSN 0022-328X
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Official URL: http://doi.org/10.1016/j.jorganchem.2003.08.041
Related URL: http://dx.doi.org/10.1016/j.jorganchem.2003.08.041
Abstract
Triallyl(aryl)silanes, stable and easily accessible arylsilanes, were found to react with aryl bromides in the presence of a palladium catalyst (PdCl2–PCy3) and tetrabutylammonium fluoride (TBAF) in good yields. The scope of the reaction is broad, and a wide variety of functional groups are tolerant. Allyl groups on Si are readily cleaved upon treatment with TBAF to form fluorosilanes, silanepolyols, siloxanes and/or their mixed forms, which might be responsible for high efficiency of the reaction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 122469 |
| Deposited On: | 02 Aug 2021 18:25 |
| Last Modified: | 02 Aug 2021 18:25 |
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