Srikrishna, A. ; Ramachary, D. B. (2007) Total Synthesis of (.+-.)-β-Microbiotene (I), (.+-.)-Microbiotol (II), (.+-.)-Cyclocuparanol (III) and (.+-.)-β-Cuparenones (IV). ChemInform, 38 (38). ISSN 0931-7597
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Official URL: http://doi.org/10.1002/chin.200738174
Related URL: http://dx.doi.org/10.1002/chin.200738174
Abstract
Total synthesis of (+/-)-beta-microbiotene, (+/-)-microbiotol, (+/-)-cyclocuparanol and their epirners along with (+/-)-beta-cuparenone has been described. A combination of orthoester Claisen rearrangement, an acid catalysed rearrangement of a diazoketone for the generation of bicyclo[4.2.1]nonanedione, a retro-Claisen condensation and an intramolecular diazoketone cyclopropanation reaction have been employed for the construction of three contiguous quaternary atoms present in cyclocuparanes.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| ID Code: | 120809 |
| Deposited On: | 05 Jul 2021 12:34 |
| Last Modified: | 05 Jul 2021 12:34 |
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