Singh, M.S. ; Singh, A.K. ; Tawade, Kiran (2002) N-BENZOIN-o-MERCAPTOANILINE AS AN EFFICIENT SYNTHON FOR ORGANOTIN(IV) COMPOUNDS Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 32 (4). pp. 639-648. ISSN 0094-5714
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Official URL: http://doi.org/10.1081/SIM-120004437
Related URL: http://dx.doi.org/10.1081/SIM-120004437
Abstract
α-Benzoin reacted with o-aminothiophenol to give a diprotic ONS Schiff base H2L. The preparation of organotin(IV) compounds of N-benzoin-o-mercaptoaniline via monoanion and dianion intermediates is reported. All of the newly synthesized compounds have been characterized by elemental analyses and spectral (IR,1H,13C and 119Sn NMR) studies. Metal coordination occurs via deprotonation of the OH and SH groups, depending upon the reaction conditions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Group. |
| ID Code: | 119724 |
| Deposited On: | 16 Jun 2021 12:06 |
| Last Modified: | 16 Jun 2021 12:06 |
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