Mukherjee, Partha Sarathi ; Das, Neeladri ; Stang, Peter J. (2004) Self-Assembly of Nanoscopic Coordination Cages Using a Flexible Tripodal Amide Containing Linker Journal of Organic Chemistry, 69 (10). pp. 3526-3529. ISSN 0022-3263
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Official URL: http://doi.org/10.1021/jo049772u
Related URL: http://dx.doi.org/10.1021/jo049772u
Abstract
Flexible, nanoscopic 3D cages containing the amide functionality were prepared via coordination-driven self-assembly from palladium(II) based 90° ditopic acceptor units and a tripod N,N‘,N‘ ‘-tris(3-pyridyl)trimesic amide. Both cages were characterized by NMR (31P, 1H) and electrospray ionization mass spectrometry. An MM2 force field simulation of one cage showed that the shape is likely pseudo trigonal bipyramidal with the diameter of the inner cavity of the cage about 1.9 nm.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 119414 |
| Deposited On: | 12 Jun 2021 16:26 |
| Last Modified: | 12 Jun 2021 16:26 |
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