Shanmugaraju, Sankarasekaran ; Bar, Arun Kumar ; Mukherjee, Partha Sarathi (2010) Ruthenium−Oxygen Coordination-Driven Self-Assembly of a RuII8Incomplete Prism: Synthesis, Structure, and Shape-Selective Molecular Recognition Study Inorganic Chemistry, 49 (22). pp. 10235-10237. ISSN 0020-1669
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Official URL: http://doi.org/10.1021/ic101823s
Related URL: http://dx.doi.org/10.1021/ic101823s
Abstract
Coordination-driven self-assembly of 1,3,5-benzenetricarboxylate (tma; 1) and oxalato-bridged p-cymeneruthenium(II) building block [Ru(2)(μ-η(4)-C(2)O(4))(MeOH)(2)(η(6)-p-cymene)(2)](O(3)SCF(3))(2) (2) affords an unusual octanuclear incomplete prism [Ru(8)(η(6)-p-cymene)(8)(tma)(2)(μ-η(4)-C(2)O(4))(2)(OMe)(4)](O(3)SCF(3))(2) (3), which exhibits a remarkable shape-selective binding affinity for neutral phenolic compounds via hydrogen-bonding interactions (p-cymene = p-(i)PrC(6)H(4)Me). Such a binding was confirmed by single-crystal X-ray diffraction analysis using 1,3,5-trihydroxybenzene as an analyte.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 118862 |
| Deposited On: | 01 Jun 2021 12:56 |
| Last Modified: | 01 Jun 2021 12:56 |
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