Kommagalla, Yadagiri ; Srinivas, Kolluru ; Ramana, Chepuri V. (2014) Ru-catalyzed branched versus linear selective C3-alkylation of 2-aroylbenzofurans with acrylates via C-H activation Chemistry - A European Journal, 20 (26). pp. 7884-7889. ISSN 0947-6539
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/chem.20...
Related URL: http://dx.doi.org/10.1002/chem.201400401
Abstract
The carbonyl-directed C3— H activation and alkylation of 2-aroylbenzo[b]furans with acrylates occurs selectively either in a linear or branched fashion, depending on the catalyst employed; [Ru(p-cymene)Cl2]2 or Ru(PPh3)3Cl2, respectively. Two alternate pathways—funded upon the differences in steric and electronic preferences of these two complexes—is proposed for the selectivity of linear versus branched products.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| Keywords: | Acrylate; Benzo[b]furan; Branched-Selective Alkylation; C[BOND]H Activation; Ruthenium |
| ID Code: | 105934 |
| Deposited On: | 01 Feb 2018 16:52 |
| Last Modified: | 01 Feb 2018 16:52 |
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