Choudhary, V. R. ; Dumbre, D. K. ; Narkhede, V. S. ; Jana, S. K. (2001) Solvent-free selective oxidation of benzyl alcohol and benzaldehyde by tert-butyl hydroperoxide using MnO-4-exchanged Mg-Al-hydrotalcite catalysts Catalysis Letters, 86 (4). pp. 229-233. ISSN 1011-372X
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Official URL: http://www.springerlink.com/content/p471hq81515g02...
Related URL: http://dx.doi.org/10.1023/A:1022620203071
Abstract
MnO- 4 (0.4 mmol/g)-exchanged Mg-Al-hydrotalcite is an active and highly selective catalyst for the oxidation of benzyl alcohol to benzaldehyde by tert-butyl hydroperoxide under reflux in the absence of solvent. It also shows high activity for the oxidation of benzaldehyde to benzoic acid. The higher the Mg/Al ratio, the higher is the catalytic activity (in both the reactions) and basicity of the hydrotalcite catalyst.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer-Verlag. |
| Keywords: | Oxidation; Benzyl Alcohol; Benzaldehyde; MnO- 4-exchanged Mg-Al-hydrotalcite |
| ID Code: | 10453 |
| Deposited On: | 03 Nov 2010 11:52 |
| Last Modified: | 28 May 2011 11:44 |
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