Mahadevan, C. ; Seshasayee, M. ; Kuppusamy, P. ; Manoharan, P. T. (1984) Crystal and molecular structure of tetra-n-butylammoniumbis(stilbenedithiolato)-nickelate(III) Journal of Crystallographic and Spectroscopic Research, 14 (2). pp. 179-191. ISSN 0277-8068
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Official URL: http://link.springer.com/article/10.1007/BF0118955...
Related URL: http://dx.doi.org/10.1007/BF01189559
Abstract
The crystal and molecular structure of the title compound, C44H56NS4Ni, are reported. Crystals are triclinic, space groupP¯1 (No. 2) withZ=2 in a unit cell of dimensionsa=8.874(2) Å,b=9.549(5) Å,c=26.025(7) Å,α=97.22(3)°,β=95.06(2)°, andγ=98.75(3)°. The structure was solved by Patterson and Fourier methods and refined by full-matrix least squares toR=0.062 for 2910 unique diffractometer data. The metal atom of the anion has an approximate square-planar configuration and the nitrogen atom of the cation an approximate tetrahedral configuration. The anions as well as the cations are well separated, the closest Ni⋯Ni and N⋯N approaches being the lattice repeat of 8.874(2) Å.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer. |
| ID Code: | 95687 |
| Deposited On: | 20 Nov 2012 11:00 |
| Last Modified: | 20 Nov 2012 11:00 |
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