Rosa, A. ; Barszczewska, W. ; Nandi, D. ; Ashok, V. ; Kumar, S. V. K. ; Krishnakumar, E. ; Brüning, F. ; Illenberger, E. (2001) Unusual temperature dependence in dissociative electron attachment to 1,4-chlorobromobenzene Chemical Physics Letters, 342 (5-6). pp. 536-544. ISSN 0009-2614
Full text not available from this repository.
Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0009-2614(01)00643-1
Abstract
Electron attachment to 1,4-chlorobromobenzene yields the ionic fragments Cl- and Br- appearing in the energy range ≈0–1 eV with Br- by about a factor of 70 more intense at room temperature. Increasing the temperature of the target molecule up to 540 K results in an unexpected temperature dependence of the cross-section in that it first increases and after passing a maximum (400 K for Br- and 460 K for Cl-) decreases. This behaviour is qualitatively interpreted by the temperature dependent population of the relevant normal modes containing the C–Cl and C–Br stretch vibration.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 95400 |
| Deposited On: | 08 Nov 2012 10:28 |
| Last Modified: | 08 Nov 2012 10:28 |
Repository Staff Only: item control page
