Adak, Laksmikanta ; Bhadra, Sukalyan ; Chattopadhyay, Kalicharan ; Ranu, Brindaban C. (2011) Amphiphilic allylation of activated alkenes by allyl acetates and allylstannanes catalyzed by palladium nanoparticles: an easy access to stereodefined substituted cyclohexene derivatives New Journal of Chemistry, 35 (2). pp. 430-437. ISSN 1144-0546
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2011...
Related URL: http://dx.doi.org/10.1039/C0NJ00624F
Abstract
An efficient vicinal double allylation of activated alkenes by allyl acetates and allylstannanes catalyzed by palladium nanoparticles, generated in situ from palladium(II) chloride, has been demonstrated. Several activated alkenes produce functionalized 1,7-octadiene derivatives in one pot. The additions of substituted allyl acetates are highly regioselective. The Grubbs cyclization of octadiene derivatives gives an easy access to stereodefined substituted cyclohexene derivatives.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 92838 |
| Deposited On: | 05 Jun 2012 10:27 |
| Last Modified: | 05 Jun 2012 10:27 |
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