Singh, Pradeep K. ; Singh, Vinod K. (2010) Enantioselective reactions catalyzed by chiral pyridine 2,6-bis(5',5'- diphenyloxazoline) - metal complexes Pure and Applied Chemistry, 82 (9). pp. 1845-1853. ISSN 0033-4545
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Official URL: http://iupac.org/publications/pac/82/9/1845/
Related URL: http://dx.doi.org/10.1351/PAC-CON-09-09-40
Abstract
A new class of tridentate pyridine-bis(oxazoline) ligand having gem-diphenyl groups at C5 of the oxazoline rings has been developed. Its metal complex exhibited high catalytic efficiency in asymmetric synthesis. We have shown that gem-diphenyl groups at C5 of the oxazoline rings are essential for getting high enantiomeric excess.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to International Union of Pure and Applied Chemistry. |
| Keywords: | Allylic Oxidation; Asymmetric Synthesis; Gem-diphenyl; Enantiomeric Excess; Friedel-crafts Alkylation; Propargylamine; Pyridine-bis(oxazoline); Tridentate Pyridine-bis(oxazoline) Ligand |
| ID Code: | 89725 |
| Deposited On: | 30 Apr 2012 14:27 |
| Last Modified: | 30 Apr 2012 14:27 |
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