Karanjule, Narayan S. ; Markad, Shankar D. ; Dhavale, Dilip D. (2006) Synthesis of pentahydroxy indolizidine alkaloids using ring closing metathesis: attempts to find the correct structure of uniflorine A Journal of Organic Chemistry, 71 (16). pp. 6273-6276. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo060823s
Related URL: http://dx.doi.org/10.1021/jo060823s
Abstract
Ring closing metathesis of D-glucose derived diene-substrate containing nitrogen functionality followed by asymmetric dihydroxylation afforded sugar substituted dihydroxylated pyrrolidines 8a-c which on 1,2-acetonide deprotection and reductive amination afforded putative uniflorine A 2a and its analogues 2b-c, respectively.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 87234 |
| Deposited On: | 16 Mar 2012 06:14 |
| Last Modified: | 19 Mar 2012 11:31 |
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