Mathur, Pradeep ; Thimmappa, B. H. S. (1988) Reactivity of tricarbonyl(η5-cyclopentadienyl)(dimethyldithiocarbamato)tungsten towards coordinatively unsaturated species Inorganica Chimica Acta, 148 (1). pp. 119-122. ISSN 0020-1693
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0020-1693(00)86021-1
Abstract
Visible light irradiation of solutions containing [(η5-C5H5)(CO)3 WSC(S)NMe2] (1) and Fe2(CO)9 or Mn2(CO)10 leads to a transmetallation type of reaction and formation of Fe(S2CNMe2)2 and Mn(CO)4(S2CNMe2) respectively. However, the reaction or 1 with M(PPh3)4, M = Pt, or Pd, leads to conversion to the dicarbonyl chelate complex [(η5C2H5(CO)2 W(S2CNMe2)].
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 83077 |
| Deposited On: | 16 Feb 2012 07:50 |
| Last Modified: | 16 Feb 2012 07:50 |
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