Synthesis and spectral characterization of diorganodiaminosilanes [(ArNH)2SiPhMe] (Ar = 2,6-iPr2C6H3; 2,4,6-Me3C6H2) and lithium silylamide [(2,6-Et2C6H3NLi)(2,6-Et2C6H3NH)SiPh2]

Palanisami, Nallasamy ; Murugavel, Ramaswamy (2006) Synthesis and spectral characterization of diorganodiaminosilanes [(ArNH)2SiPhMe] (Ar = 2,6-iPr2C6H3; 2,4,6-Me3C6H2) and lithium silylamide [(2,6-Et2C6H3NLi)(2,6-Et2C6H3NH)SiPh2] Journal of Organometallic Chemistry, 691 (15). 3260- 3266. ISSN 0022-328X

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.jorganchem.2006.03.039

Abstract

Aminosilanes bearing bulky substituents on nitrogen centers, [(ArNH)2SiPhMe](Ar = (Ar = 2,6-iPr2C6H3(1), 2,4,6-Me3C6H2)(2)) and half-sandwich lithium silylamide [(2,6-Et2C6H3NLi(2,6-Et2C6H3NH)SiPh2] (3) have been prepared and characterized by elemental analysis, IR, EI mass and NMR (1H and 29Si) spectroscopic studies. The solid state structures of 2 and 3 have been determined by single crystal X-ray diffraction studies. The molecule 2 has a C1 symmetry due to the steric crowding, and the two N-H protons are approximately trans to each other. The amido nitrogen atoms in 2 show significant deviation from trigonal-planar geometry, and as a result, the observed Si-N bonds are marginally longer than those observed in aminosilanes with planar nitrogen atoms. The molecule 3 exists as discrete dimer with an inversion center. The Li ion in 3 forms intramolecular p-complex with the neighboring aryl (2,6-Et2C6H3) group, to form a half-sandwich lithium silylamide.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Aminosilanes; Half-sandwich Lithium; NMR Spectroscopy; X-ray Diffraction
ID Code:75174
Deposited On:22 Dec 2011 03:22
Last Modified:22 Dec 2011 13:25

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