Perkas, Nina ; Koltypin, Yuri ; Palchik, Oleg ; Gedanken, Aharon ; Chandrasekaran, S. (2001) Oxidation of cyclohexane with nanostructured amorphous catalysts under mild conditions Applied Catalysis A: General, 209 (1-2). pp. 125-130. ISSN 0926-860X
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/S09268...
Related URL: http://dx.doi.org/10.1016/S0926-860X(00)00750-X
Abstract
The oxidation of cyclohexane with molecular oxygen (1 atm) in the presence of isobutyraldehyde catalyzed by nanostructured iron and cobalt oxides and iron supported on titania has been studied. It was found that highly dispersed transition metals oxide is more effective for oxidation than the corresponding zero valent powders. In the titania supported catalysts iron exists as iron (III) oxide segregated to the surface layers and stabilized by titania. This form is the most active in the cyclohexane oxidation under mild conditions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Cyclohexane Oxidation; Sonication Method; Transition Metal Oxide; Iron (III) Supported on Titania |
| ID Code: | 7125 |
| Deposited On: | 25 Oct 2010 12:31 |
| Last Modified: | 28 May 2011 11:28 |
Repository Staff Only: item control page
