Translational energy spectrometric and quantum chemical study of CSq+ (q=1, 2) radicals: charge stripping and dissociation

Krishnamurthi, V. ; Krishamurthy, M. ; Marathe, V. R. ; Mathur, D. (1992) Translational energy spectrometric and quantum chemical study of CSq+ (q=1, 2) radicals: charge stripping and dissociation Journal of Physics B: Atomic, Molecular and Optical Physics, 25 (23). pp. 5149-5162. ISSN 0953-4075

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Official URL: http://iopscience.iop.org/0953-4075/25/23/018

Related URL: http://dx.doi.org/10.1088/0953-4075/25/23/018

Abstract

A combined experimental and theoretical investigation has been carried out on CS+ and CS2+ radical ions. Ion translational energy spectrometry has been applied to study charge stripping of CS+ ions to yield metastable CS2+ ions and to study the energetics of spontaneous and collision-induced dissociation of these metastable doubly charged ions of CS. All-electron ab initio molecular orbital calculations, inclusive of fairly large-scale configuration interaction procedures, have been carried out to compute the potential energy functions of the different ionic systems involved in the collision processes studied experimentally.

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