Photochemical behaviour of 4-styrylcoumarin polymorphs in the crystalline state

Vishnumurthy, Kodumuru ; Row, Tayur N. Guru ; Venkatesan, Kailasam (2002) Photochemical behaviour of 4-styrylcoumarin polymorphs in the crystalline state Photochemical and Photobiological Sciences, 1 (10). pp. 799-802. ISSN 1474-905X

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2002...

Related URL: http://dx.doi.org/10.1039/B204387D

Abstract

Addition of a small amount of coumarin during crystallization produces new polymorphic modifications in 4-styrylcoumarin and 4-(3-fluorostyryl)coumarin, which are photolabile. Interestingly, upon irradiation polymorphic modification of 4-(3-fluorostyryl)coumarin produces a mirror-symmetric photodimer in contrast to the centrosymmetric photodimer obtained without addition of coumarin during crystallization.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:66594
Deposited On:27 Oct 2011 04:16
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