Vivekanandam, T. S. ; Gopalan, A. ; Vasudevan, T. ; Umapathy, S. (2000) Sonochemical cyclopolymerization of diallylamine European Polymer Journal, 36 (2). pp. 385-392. ISSN 0014-3057
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0014-3057(99)00071-3
Abstract
Cyclopolymerization of a symmetrical nonconjugated diolefin, diallylamine was found possible in the presence of ultrasound and peroxodisulphate. The rate of polymerization, Rp showed first-and half-order dependencies on diallylamine and peroxodisulphate concentration, respectively. The results are explained through a proposed mechanism involving alternating intramolecular and intermolecular propagation reactions. The rate parameters for the cyclopolymerization are evaluated. The role of ultrasound in initiating the cyclopolymerization is discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Cyclopolymerization; Diallylamine; Peroxodisulphate; Ultrasound; Mechanism; Rate Parameters |
| ID Code: | 64995 |
| Deposited On: | 15 Oct 2011 12:33 |
| Last Modified: | 15 Oct 2011 12:33 |
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