Yadav, Jhillu S. ; Rami Reddy, N. ; Bala Murali Krishna, B. ; Vijaya Vardhan, Ch. ; Subba Reddy, Basi V. (2010) Substrate-controlled stereoselective synthesis of ophiocerin C Synthesis, 2010 (10). pp. 1621-1624. ISSN 0039-7881
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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-0029-1218708
Abstract
A novel stereoselective total synthesis of ophiocerin C was accomplished starting from L-(+)-tartaric acid. The C3,C4 vic-diol moiety was obtained from tartaric acid, and the stereogenic centre at C6 was created by substrate-controlled epoxidation and subsequent regioselective cleavage of the epoxide ring.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Wittig Reactions; Tartaric Acid; Epoxidations; Ring Opening; Ophiocerin C; Stereoselective Synthesis |
| ID Code: | 63121 |
| Deposited On: | 28 Sep 2011 03:46 |
| Last Modified: | 28 Sep 2011 03:46 |
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