Yadav, J. S. ; Reddy, B. V. S. ; Sridhar Reddy, M. ; Parimala, G. (2003) InBr3-catalyzed alkynylation and allylation of acid chlorides: a facile synthesis of alkynyl and allyl ketones Synthesis, 2003 (15). pp. 2390-2394. ISSN 0039-7881
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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-2003-42438
Abstract
Alkynylsilanes and allyltrimethylsilane undergo smooth coupling with acid chlorides in the presence of 5 mol% of indium tribromide under mild conditions to afford the corresponding α,β-acetylenic ketones and β,γ-unsaturated ketones in excellent yields in a short reaction time with high selectivity.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Indium Reagents; Acid Chlorides; α,β- and β,γ-unsaturated Ketones |
| ID Code: | 62947 |
| Deposited On: | 24 Sep 2011 04:44 |
| Last Modified: | 24 Sep 2011 04:44 |
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