Yadav, Jhillu S. ; Subba Reddy, Basi V. ; Bala Murali Krishna, B. (2008) IBX: a novel and versatile oxidant for electrophilic thiocyanation of indoles, pyrrole and arylamines Synthesis, 2008 (23). pp. 3779-3782. ISSN 0039-7881
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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-0028-1083636
Abstract
The direct thiocyanation of indoles and pyrrole with ammonium thiocyanate has been achieved using o-iodoxybenzoic acid (IBX) under mild and neutral conditions to produce indol-3-yl and pyrrol-2-yl thiocyanates, respectively, in excellent yields and with high selectivity. This method is effective even with N-substituted arylamines for the preparation of aryl thiocyanates.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | O-iodoxybenzoic Acid; Electrophilic Substitution; Indoles; Aryl Thiocyanates; Heteroaryl Thiocyanates |
| ID Code: | 62931 |
| Deposited On: | 24 Sep 2011 04:56 |
| Last Modified: | 24 Sep 2011 04:56 |
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