Krishnan, Retheesh ; Gopidas, Karical R. (2011) β-cyclodextrin as an end-to-end connector Journal of Physical Chemistry, 2 (17). pp. 2094-2098. ISSN 0022-3654
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jz2009117
Related URL: http://dx.doi.org/10.1021/jz2009117
Abstract
Interaction of β-cyclodextrin (β-CD) with a ditopic molecule having adamantane (AD) at one end and a pyromellitic diimide (PMDI) moiety at the other is studied. The AD moiety undergoes inclusion binding with the β-CD cavity, and the PMDI undergoes binding with the primary rim of β-CD. In an equimolar solution of β -CD and the ditopic molecule in water, β-CD accommodates both modes of complexation simultaneously, leading to the formation of long fibers. The fibers get entangled to give a supramolecular hydrogel with very high water content.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 62102 |
| Deposited On: | 16 Sep 2011 04:38 |
| Last Modified: | 16 Sep 2011 04:38 |
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