Kumar, Venugopal K. Ratheesh ; Gopidas, Karical R. (2011) Palladium nanoparticle-cored G1-dendrimer stabilized by carbon-Pd bonds: synthesis, characterization and use as chemoselective, room temperature hydrogenation catalyst Tetrahedron Letters, 52 (24). pp. 3102-3105. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2011.04.011
Abstract
Palladium nanoparticle-cored Frechet type G1-dendrimer (Pd-G1) stabilized by Pd-carbon bonds is synthesized and characterized by IR, NMR, UV-Vis and TEM. Pd-G1 was found to be a highly efficient, chemoselective and reusable catalyst for the room temperature hydrogenation of carbon-carbon multiple bonds. Reducible functionalities like CHO, CO, COOR, CN, NO2 and halogens were unaffected. Pd-G1 is projected as an efficient catalyst for the selective hydrogenation of carbon-carbon multiple bonds in multifunctional organic molecules.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 62092 |
| Deposited On: | 16 Sep 2011 04:38 |
| Last Modified: | 16 Sep 2011 04:38 |
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