Palladium nanoparticle-cored G1-dendrimer stabilized by carbon-Pd bonds: synthesis, characterization and use as chemoselective, room temperature hydrogenation catalyst

Kumar, Venugopal K. Ratheesh ; Gopidas, Karical R. (2011) Palladium nanoparticle-cored G1-dendrimer stabilized by carbon-Pd bonds: synthesis, characterization and use as chemoselective, room temperature hydrogenation catalyst Tetrahedron Letters, 52 (24). pp. 3102-3105. ISSN 0040-4039

Full text not available from this repository.

Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2011.04.011

Abstract

Palladium nanoparticle-cored Frechet type G1-dendrimer (Pd-G1) stabilized by Pd-carbon bonds is synthesized and characterized by IR, NMR, UV-Vis and TEM. Pd-G1 was found to be a highly efficient, chemoselective and reusable catalyst for the room temperature hydrogenation of carbon-carbon multiple bonds. Reducible functionalities like CHO, CO, COOR, CN, NO2 and halogens were unaffected. Pd-G1 is projected as an efficient catalyst for the selective hydrogenation of carbon-carbon multiple bonds in multifunctional organic molecules.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:62092
Deposited On:16 Sep 2011 04:38
Last Modified:16 Sep 2011 04:38

Repository Staff Only: item control page