Sarish, Sankaranarayana Pillai ; Nembenna, Sharanappa ; Roesky, Herbert W. ; Ott, Holger ; Pal, Aritra ; Stalke, Dietmar ; Dutta, Sudipta ; Pati, Swapan K. (2009) Soluble molecular dimers of CaO and SrO stabilized by a Lewis Acid Angewandte Chemie International Edition, 48 (46). pp. 8740-8742. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.20...
Related URL: http://dx.doi.org/10.1002/anie.200904054
Abstract
The reaction between a β-diketiminate aluminum methyl hydroxide and [M{N(SiMe3)2}2(thf)2] (M=Ca, Sr) results in alkaline-earth-metal oxides such as [{LAl(Me)(μ-O)Ca(thf)}2] (see core structure; L is deprotonated β-diketiminate CH{C(CH2)}(CMe)(2,6-iPr2C6H3N)2). These soluble complexes are dimeric in the solid state and contain unprecedented M2O2 cores.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Alkaline Earth Metals; Calcium; Hydroxides; Oxides; Strontium |
| ID Code: | 60839 |
| Deposited On: | 12 Sep 2011 07:24 |
| Last Modified: | 12 Sep 2011 07:24 |
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