Mohapatra, Debendra K. ; Samad Hossain, Sk. ; Dhara, Santu ; Yadav, J. S. (2010) Application of desymmetrization protocol for the formal total synthesis of emericellamide B Tetrahedron Letters, 51 (23). pp. 3079-3082. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2010.04.015
Abstract
A highly convergent formal total synthesis of emericellamide B, a 19-membered antibacterial depsipeptide is described. The key feature of the strategy is the generation of four stereogenic centers from a bicyclic precursor via desymmetrization technique and utilization for emericellamide B and related natural product synthesis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Emericellamide B; Cytotoxicity; Desymmetrization; Barton-Mccombie Reaction; Wittig Homologation |
| ID Code: | 59552 |
| Deposited On: | 07 Sep 2011 05:58 |
| Last Modified: | 07 Sep 2011 05:58 |
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