Yadav, J. S. ; Samad Hossain, Sk. ; Mohapatra, Debendra K. (2010) Synthesis of C15-C27 segment of venturicidine X by utilizing desymmetrization protocol Tetrahedron Letters, 51 (32). pp. 4179-4181. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2010.05.148
Abstract
We have achieved the synthesis of C15-C27 fragment of venturicidine X using desymmetrization protocol, substrate-controlled Grignard reaction, Barton-McCombie reaction, Sharpless epoxidation, and TBSOTf-mediated rearrangement to produce the aldol product through a non-aldol route as the key step following 23 longest linear sequences with 6.4% overall yield starting from a known intermediate 11.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Venturicidines A,B, and X; Desymmetrization; Barton-McCombie Reaction; Wittig Reaction; Sharpless Asymmetric Epoxidation |
| ID Code: | 58927 |
| Deposited On: | 02 Sep 2011 03:41 |
| Last Modified: | 02 Sep 2011 03:41 |
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