Yadav, J. S. ; Subba Reddy, B. V. ; Shiva Shankar, K. ; Swamy, T. (2010) The reductive etherification of carbonyl compounds using polymethylhydrosiloxane activated by molecular iodine Tetrahedron Letters, 51 (1). pp. 46-48. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2009.10.063
Abstract
Aldehydes and ketones undergo a smooth reductive etherification by polymethylhydrosiloxane (PMHS) in the presence of a catalytic amount of molecular iodine under mild conditions to afford the corresponding symmetrical ethers in excellent yields. This new reagent system (PMHS/I) provides a simple and convenient route for the preparation of symmetrical ethers from carbonyl compounds.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Polymethylhydrosiloxane; Molecular Iodine; Carbonyl Compounds; Reductive Etherification; Ethers |
| ID Code: | 58875 |
| Deposited On: | 02 Sep 2011 03:36 |
| Last Modified: | 02 Sep 2011 03:36 |
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