Yadav, J. S. ; Sathaiah, K. ; Srinivas, R. (2009) Total synthesis of (−)-baconipyrone C Tetrahedron, 65 (17). pp. 3545-3552. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tet.2008.12.049
Abstract
A highly stereoselective asymmetric total synthesis of marine polypropionate (−)-baconipyrone C has been achieved. Utilization of desymmetrization technique to create five stereogenic centres, Sharpless epoxidation, Gilman's reaction and resolution of methyl group using enzyme PS-C is the highlight of the synthesis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | (−)-Baconipyrone C; Desymmetrization; Enzymatic Resolution; Sharpless Epoxidation; Gilmans' Reaction |
| ID Code: | 58868 |
| Deposited On: | 02 Sep 2011 03:33 |
| Last Modified: | 02 Sep 2011 03:33 |
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