Yadav, J. S. ; Bezawada, Padmavani ; Chenna, Venugopal (2009) Formal total synthesis of borrelidin: synthesis of C1-C11 fragment via desymmetrization strategy Tetrahedron Letters, 50 (27). pp. 3772-3775. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2009.03.196
Abstract
A stereoselective formal total synthesis of borrelidin is described. The synthetic strategy for synthesis of C1-C11 fragment features desymmetrization of Diels-Alder adduct, Sharpless asymmetric epoxidation, regioselective opening of chiral epoxide, and alkylation using Evans chiral auxiliary.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Borrelidin; Desymmetrization; Sharpless Asymmetric Epoxidation; Evan's Chiral Auxiliary |
| ID Code: | 58829 |
| Deposited On: | 02 Sep 2011 03:35 |
| Last Modified: | 02 Sep 2011 03:35 |
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