Sabitha, Gowravaram ; Siva Sankara Reddy, S. ; Yadav, J. S. (2010) Total synthesis of cryptopyranmoscatone B1 from 3,4,6-tri-O-acetyl-D-glucal Tetrahedron Letters, 51 (48). pp. 6259-6261. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2010.09.085
Abstract
The first stereoselective total synthesis of the natural cryptopyranmoscatone B1 has been accomplished from 3,4,6-tri-O-acetyl-D-glucal. In addition to the double cross-metathesis reaction, a tandem nucleophilic addition-diastereoselective reduction of an in situ generated oxocarbenium cation have been used as key steps to assemble the glycoside moiety of the target molecule.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Cryptopyranmoscatone; Styryllactone; 3,4,6-tri-O-acetyl-D-glucal; Cross-metathesis; β-C-glycoside |
| ID Code: | 58807 |
| Deposited On: | 02 Sep 2011 03:42 |
| Last Modified: | 02 Sep 2011 03:42 |
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