Stereoselective total synthesis of stagonolide E

Sabitha, Gowravaram ; Padmaja, P. ; Narayana Reddy, P. ; Jadav, Surender Singh ; Yadav, J. S. (2010) Stereoselective total synthesis of stagonolide E Tetrahedron Letters, 51 (47). pp. 6166-6168. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2010.09.072

Abstract

The first total synthesis of a 10-membered macrolide, stagonolide E is described from readily available 4-penten-1-ol. The synthetic strategy involves Jacobsen's kinetic resolution, Sharpless epoxidation, Stille-Gennari, and Yamaguchi lactonization as key reactions.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Macrolide; Jacobsen's Kinetic Resolution; Sharpless Epoxidation; Stille-Gennari; Yamaguchi Lactonization
ID Code:58797
Deposited On:02 Sep 2011 03:42
Last Modified:02 Sep 2011 03:42

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