Acetyl chloride-silver nitrate-acetonitrile: a reagent system for the synthesis of 2-nitroglycals and 2-nitro-1-acetamido sugars from glycals

Kancharla, Pavan K. ; Suman Reddy, Y. ; Dharuman, Suresh ; Vankar, Yashwant D. (2011) Acetyl chloride-silver nitrate-acetonitrile: a reagent system for the synthesis of 2-nitroglycals and 2-nitro-1-acetamido sugars from glycals Journal of Organic Chemistry, 76 (14). pp. 5832-5837. ISSN 0022-3263

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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo200475h

Related URL: http://dx.doi.org/10.1021/jo200475h

Abstract

A new reagent system comprising acetyl chloride, silver nitrate, and acetonitrile has been developed for the synthesis of 2-nitroglycals from the corresponding glycals. Under certain conditions, the formation of 2-nitro-1-acetamido sugars has also been observed. In addition, a few other non-carbohydrate-derived olefins also gave the corrresponding conjugated nitroolefins.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:58186
Deposited On:31 Aug 2011 06:43
Last Modified:31 Aug 2011 06:43

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