Maya, Vishnu ; Raj, Monika ; Singh, Vinod K. (2007) Highly enantioselective organocatalytic direct aldol reaction in an aqueous medium Organic Letters, 9 (13). pp. 2593-2595. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol071013l
Related URL: http://dx.doi.org/10.1021/ol071013l
Abstract
We have demonstrated that small organic molecules 1 and 2 catalyzed the direct aldol reaction of both acyclic and cyclic ketones with different aldehydes in an excess of water/brine. Excellent enantioselectivities up to >99% and diastereoselectivities up to 99% with very good yields were obtained by using much lower catalyst loadings (0.5 mol %).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 55426 |
| Deposited On: | 18 Aug 2011 08:44 |
| Last Modified: | 18 Aug 2011 08:44 |
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