Strict self-assembly of [Fe(cyclam)]3+ and [hydrogenbis(1,1'-ferrocenedicarboxylate)]3− into a novel mixed-valent one-dimensional polymer containing an FeIIIN4O2 chromophore

Christie, Sean D. ; Subramanian, S. ; Thompson, L. K. ; Zaworotko, M. J. (1994) Strict self-assembly of [Fe(cyclam)]3+ and [hydrogenbis(1,1'-ferrocenedicarboxylate)]3− into a novel mixed-valent one-dimensional polymer containing an FeIIIN4O2 chromophore Journal of the Chemical Society . pp. 2563-2564. ISSN 0368-1769.

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1994...

Related URL: http://dx.doi.org/10.1039/C39940002563

Abstract

trans-[FeIII(cyclam)][{Fc(CO2)2}2H], 1, (cyclam = 1,4,8,11-tetraazacyclotetradecane; [Fc(CO2)2]2−= 1,1'-ferrocenedicarboxylate) strictly self-assembles via FeIII-carboxylate covalent bonds and hydrogenbiscarboxylate hydrogen bonds to form a one-dimensional polymer that contains the first crystallographically characterized FeIIIN4O2 chromopore.

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